崔　亨波    Cui Hengbo 研究員 1971年生まれ   1993年6月 中国　延辺大学　化学科　卒業 1996年6月 中国　延辺大学　化学科　修士課程　修了 2003年3月 東京大学大学院　理学系研究科化学専攻　博士課程　修了 （スペクトル化学研究センター　小林昭子教授） 博士論文　"希土類金属錯体をアニオンとする有機伝導体および類似体の系統的研究" 1996年7月 延辺大学　薬学院　助手 2003年4月 分子科学研究所　CREST研究員（小林速男　教授） 2007年6月 National High Magnetic Field Laboratory　ポスドク研究員（James　Brooks教授） 2009年4月 理化学研究所　加藤分子物性研究室　基礎科学特別研究員（加藤 礼三　主任） 2012年4月 理化学研究所　加藤分子物性研究室　ASI研究員（加藤 礼三　主任） ・分子性導体、磁性伝導体の作成および物性研究 ・ダイアモンドアンビルを用いた超高圧下での物性研究 ・新規なポーラス誘電物質の開発 ・金属錯体を用いた新規分子性物質の開発 T. Lee, Y. Oshima, H. B. Cui, and R. Kato Detailed X-band Studies of the π-d Molecular Conductor λ-(BETS)2FeCl4: Observation of Anomalous Angular Dependence of the g-value J. Phys. Soc. Jpn. 87, 114702/1-8 (2018).    New! Y. Oshima, H. B. Cui, and R. Kato Antiferromagnetic Insulating Ground State of Molecular π-d System λ-(BETS)2FeCl4 (BETS = Bis(ethylenedithio)tetraselenafulvalene): A Theoretical and Experimental Review Magnetochemistry, 3(1), 10/1-16, (2017). R. Kato, H. B. Cui, T. Tsumuraya, T. Miyazaki, and Y. Suzumura Emergence of the Dirac Electron System in a Single-Component Molecular Conductor under High Pressure J. Am. Chem. Soc., 139(5), 1770-1773 (2017). M. Souto, H. B. Cui, M. Pena-Alvarez, V. G. Baonza, H. O. Jeschke, M. Tomic, R. Valenti, D. Blasi, I. Ratera, C. Rovira, and J. Veciana Pressure-Induced Conductivity in a Neutral Non-planar Spin-localized Radical J. Am. Chem. Soc., 138(36), 11517-11525 (2016). H. B. Cui, A. F. Bangura, and R. Kato High-Pressure Resistivity Measurement under High Quality Hydrostatic Condition The Review of High Pressure Science and Technology, 25(4), 292-297 (2015). T. Ishikawa, S. A. Hayes, S. Keskin, G. Corthey, M. Hada, K. Pichugin, A. Marx, J. Hirscht, K. Shionuma, K. Onda, Y. Okimoto, S. Koshihara, T. Yamamoto, H. B. Cui, M. Nomura, Y. Oshima, M. A. Jawad, R. Kato, and R. J. D. Miller Direct Observation of Collective Modes Coupled to Molecular Orbital-Driven Charge Transfer Science, 350(6267), 1501-1505 (2015). H. B. Cui, T. Tsumuraya, T. Miyazaki, Y. Okano, and R. Kato Pressure-Induced Metallic Conductivity in the Single-Component Molecular Crystal [Ni(dmit)2] Eur. J. Inorg. Chem., 2014(24), 3837-3840 (2014). H. B. Cui, H. Kobayashi, S. Ishibashi, M. Sasa, F. Iwase, R. Kato, and A. Kobayashi A Single-Component Molecular Superconductor J. Am. Chem. Soc., 136(21), 7619-7622 (2014). S. Yasuzuka, Y. Idobata, B. Zhou, A. Kobayashi, K. Katoh, H. B. Cui, R. Kato, M. Tokumoto, and H. Kobayashi Hidden Spin Scattering Behavior in [Ni1-xCux(tmdt)2] System with Unprecedentedly Strong π-d Interaction J. Phys. Soc. Jpn., 83, 074701/1-074701/5 (2014). K. Otsuka, H. Iikubo, T. Kogure, Y. Takano, K. Hiraki, T. Takahashi, H. B. Cui, and R. Kato Antiferromagnetic Ordering in Quasi-Triangular Localized Spin System, β -Et2Me2P[Pd(dmit)2]2, Studied by 13CNMR J. Phys. Soc. Jpn., 83, 054712/1-054712/6 (2014). H. M. Yamamoto, Y. Kawasugi, H. B. Cui, M. Nakano, Y. Iwasa, and R. Kato Asymmetric Phase Transitions Observed at the Interface of a Field-Effect Transistor Based on an Organic Mott Insulator Euro. J. Inorg. Chem.(Online ver.) (2014). N. Takubo, N. Tajima, H. M. Yamamoto, H.-B. Cui and R. Kato Lattice Distortion Stabilizes the Photoinduced Metallic Phase in the Charge-Ordered Organic Salts (BEDT-TTF)3X2 (X=ReO4, ClO4) Phys. Rev. Lett. 110, 227401/1-227401/5 (2013). Y. Kosaka, H. M. Yamamoto, A. Tajima, A. Nakao, H. B. Cui, and R. Kato Supramolecular Ni(dmit)2 Salts with Halopyridinium Cations -Development of Multifunctional Molecular Conductors with the Use of Competing Supramolecular Interactions CrystEngComm, 15, 3200-3211 (2013). B. Zhou, Y. Idobata, A. Kobayashi, H. B. Cui, R. Kato, R. Takagi, K. Miyagawa, K. Kanoda, and H. Kobayashi Single-Component Molecular Conductor [Cu(dmdt)2] with Three-Dimensionally Arranged Magnetic Moments Exhibiting a Coupled Electric and Magnetic Transition J. Am. Chem. Soc., 134(30), 12724-12731 (2012). Y. Oshima, H. Nojiri, S. Uji, J. S. Brooks, T. Tokumoto, H..B Cui, R. Kato, A. Kobayashi, and H. Kobayashi Breakdown of the Field-Induced Superconductivity by Dynamical Spin Reversal Phys. Rev. B, 86, 024525/1-024525/7 (2012). R. Kato and C. Hengbo Cation Dependence of Crystal Structure and Band Parameters in a Series of Molecular Conductors, β'-(Cation)[Pd(dmit)2]2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate) Crystals, 2(3), 861-874 (2012). B. Zhou, A. Kobayashi, H. B. Cui, L. S. Long, H. Fujimori, and H. Kobayashi Anomalous Dielectric Behavior and Thermal Motion of Water Molecules Confined in Channels of Porous Coordination Polymer Crystals J. Am. Chem. Soc., 133(15), 5736-5739 (2011). J. Lieffrig, H. M. Yamamoto, T. Kusamoto, H. Cui, O. Jeannin, M. Fourmigue, and R. Kato Halogen-Bonded, Eight-fold PtS-Type Interpenetrated Supramolecular Network. A Study toward Redundant and Cross-Bar Supramolecular Nanowire Crystal Cryst. Growth Des., 11(10), 4267-4271 (2011). E. Steven, H. B. Cui, A. Kismarahardja, J. S. Brooks, D. Graf, and H. Kobayashi Role of Anion Size, Magnetic Moment, and Disorder on the Properties of the Organic Conductor κ-(BETS)2Ga1-xFexCl4-yBry Physica B: Condensed Matter, 405, S295-S298 (2010). H. Kobayashi, B. Zhou, A. Kobayashi, Y. Okano, E. Nishibori, M. Sakata, H. Cui, and J. Brooks Resistivity Measurements on TMTTeN and [Ni(ptdt)2] above 20 GPa and Electrical and Structural Studies on [Au(tmdt)2] Physica B: Condensed Matter, 405, S303-S307 (2010). B. Zhou, A. Kobayashi, Y. Okano, H. B. Cui, D. Graf, J. S. Brooks, T.Nakashima, S. Aoyagi, E. Nishibori, M. Sakata, and H. Kobayashi Structural Anomalies Associated with Antiferromagnetic Transition ofSingle-Component Molecular Metal [Au(tmdt)2] Inorg. Chem. 48(21), 10151-10157 (2009). H.B. Cui, D. Graf, J. S. Brooks, H. Kobayashi Pressure-Dependent Metallic and Superconducting Phases in a Germanium Artificial Metal Phys. Rev. Lett. 102, 237001-4 (2009). H. B. Cui, J. S. Brooks, A. Kobayashi, and H. Kobayashi Metallization of the Single Component Molecular Semiconductor [Ni(ptdt)2] under Very High Pressure J. Am. Chem. Soc. 131, 6358-6359 (2009). H. B. Cui, J. Brooks, D. Graf, Y. Okano, H. L. Sun, and H. Kobayashi Electrical Properties of New Organic Conductor (BEST)2InBr4 [BEST = Bis(ethylenediseleno)tetrathiafulvalene] up to 10.8 GPa and Antiferromagnetic Transition of (BEST)2FeBr4 Inorg. Chem. 48, 4268-4270 (2009) K. Awaga, Y. Umezono, W. Fujita, H. Yoshikawa, H. B. Cui, H. Kobayashi, S. S. Staniland, and N. Robertson Diverse magnetic and electrical properties of molecular solids containing the thiazyl adical BDTA Inorg. Chem. Acta., 361, 3761-3770 (2008) L. L.Lumata, ,J. S. Brooks, , P. L. Kuhns, A. P. Reyes, S. E. Brown, H. B. Cui, R. C. Haddon Se77 NMR investigation of the field-induced spin-density-wave transitions in (TMTSF)2ClO4 Phys. Rev. B., 78, 020407(R) 2008. K. Takahashi, H. B. Cui, Y. Okano, H. Kobayashi, H. Mori, H. Tajima, Y. Einaga, O. Sato Evidence of the chemical uniaxial strain effect on electrical conductivity in the spin-crossover conducting molecular system: [Fe-III(qnal)(2)][Pd(dmit)(2)](5)center dot Acetone J. Am. Chem. Soc., 130, 6688-6689 (2008). H. B. Cui, B. Zhou, L.-S. Long, Y. Okano, H. Kobayashi, and A. Kobayashi Porous Coordination Polymer Crystal Containing One-dimensional Water Chains Exhibiting Guest-Induced Lattice Distortion and Dielectric Anomaly Angew. Chem. Int. Ed. 47, 3376-3380 (2008). H. B. Cui, Y. Okano, B. Zhou, A. Kobayashi, and H. Kobayashi Electrical Resistivity of Tetramethyltetratelluronaphtalene Crystal at Very High Pressure -Examination of the dondition of Metallizaion of π Molecular Crystal J. Am. Chem. Soc. 130, 3738-3739 (2008). E. Fujiwara, K. Yamamoto, M. Shimamura, B. Zhou, A. Kobayashi, K. Takahashi, Y. Okano, H. B. Cui, and H. Kobayashi (nBu4N)[Ni(dmstfdt)2]: A Planar Nickel Coordination Complex with an Extended-TTF Ligand Exhibiting Metallic Conduction, Metal-Insulator Transition, and Weak Ferromagnetism Chem. Mater. 19, 553-558 (2007). H. B. Cui, H. Kobayashi, and A. Kobayashi Phase Diagram and Anomalous Constant Resistivity State of Magnetic Organic Superconducting Alloy,&lambda-(BETS)2FexGa1-xCl4 J. Mater. Chem. 17, 45-48 (2007). H. B. Cui, Z. M. Wang, K. Takahashi, Y. Okano, H. Kobayashi, and A. Kobayashi Ferroelectric Porous Molecular Crystal, [Mn3(HCOO)6](C2H5OH), Exhibiting Ferrimagnetic Transition J. Am. Chem. Soc. 128, 15074-15075 (2006). S. Uji, T. Terashima, M. Nishimura, Y. Takahide, T. Konoike, K. Enomoto, H. B. Cui, H. Kobayashi, A. Kobayashi, H. Tanaka, M. Tokumoto, E. S. Choi, T. Tokumoto, D. Graf, and J. S. Brooks Vortex Dynamics and the Fulde-Ferrell-Larkin-Ovchinnikov State in a Magnetic-Field-Induced Organic Superconductor Phys. Rev. Lett. 97, 157001-4 (2006) H. Tanaka, S. Hara, M. Tokumoto, H. B. Cui, H. Kobayashi, and A Kobayashi Observation of antiferromagnetic spin-flop transition in gamma-type BETS salts using AFM microcantilever J. Low Temp. Phys. 142 (3-4), 605-608 (2006). K. Takahashi, H. B. Cui, Y. Okano, H. Kobayashi, Y. Einaga, and O. Sato Electrical Conductivity Modulation Coupled to a High-Spin-Low-Spin Conversion in the Molecular System [FeIII(qsal)2][Ni(dmit)2]3・CH3CN・H2O Inorg. Chem., 45, 5739-5741 (2006). S. Fujiyama, M. Takigawa, J. Kikuchi, H. B. Cui. H. Fujiwara, and H. Kobayashi Compensation of Effective Field in the Field-Induced Superconductor Κ-(BETS)2FeBr4 Observed by 77Se NMR Phys. Rev. Lett. 96, 217001 (2006). T. Kusamoto, E. Fujiwara, A. Kobayashi, H. B. Cui, T. Otsuka, Y. Okano, H. Fujiwara, and H. Kobayashi BDT-TTP-Based π Conductors Containing Dicalent Magnetic and Non-Magnetic Inorganic Anions, [MCl4]2- (M = Co, Mn, Zn) Bull. Chem. Soc. Jpn., 79, 527-536 (2006). B. Zhang, Z. M. Wang, Y. Zhang, K. Takahashi, Y. Okano, H. B. Cui, H. Kobayashi, K. Inoue, M. Kurmoo, F. L. Pratt, and D. B. Zhu Hybrid Organic-Inorganic Conductor with a Magnetic Chain Anion: -BETS2[FeIII(C2O4)Cl2] [BETS = Bis(ethylenedithio)tetraselenafulvalene] Inorg. Chem., 45, 3275 - 3280 (2006). B. Zhou, M. Shimamura, E. Fujiwara, A. Kobayashi, T. Higashi, E. Nishibori, M. Sakata, H. B. Cui, K. Takahashi, and H. Kobayashi Magnetic Transitions of Single-Component Molecular Metal [Au(tmdt)2] and Its Alloy Systems J. Am. Chem. Soc. 128, 3872 - 3873 (2006). S. Otsubo, H. B. Cui, H.-J. Lee, H. Fujiwara, K. Takahashi, Y. Okano, H. Kobayashi A Magnetic Organic Conductor Based on a Donor with a Stable Radical and a Magnetic Anion - A Step to Magnetic Organic Metals with Two Kinds of Localized Spin Systems Chem. Lett., 35, 130-131 (2006). S. Otsubo, K. Takahashi, H. B. Cui, Y. Okano, and H. Kobayashi Organic Metals Based on an Ssymmetric π Donor PEDT-TSF, (PEDT-TSF)2FeX4 (PEDT-TSF = pyrazinoethylenedithiotetraselenafulvalene; X = Cl, Br) Chem. Lett., 34,1598-1599 (2005). S. Fujiyama, M. Takigawa, J. Kikuchi, K. Kodama, T. Nakamura, E. Fujiwara, H. Fujiwara, H. Cui, and H. Kobayashi Nuclear Spin-Lattice Relaxation in Κ-(BETS)2FeBr4 Synth. Met., 154, 253-256 (2005). Y. Oshima, E. Jobiliong, J. S. Brooks, S. A. Zvyagin, J. Krzystek, H. Tanaka, A. Kobayashi, H. B. Cui, and H. Kobayashi EMR Measurements of Field-induced Superconductor λ-(BETS)2FexGa1-xCl4 Synth. Met. 153, 365-368 (2005). H. B. Cui, K. Takahashi, Y. Okano, H. Kobayashi, Z. M. Wang, and A. Kobayashi Dielectric Properties of Porous Molecular Crystals That Contain polar Molecules Angew.Chem. Int. Ed. 44(40), 6508-6512 (2005). K. Takahashi, H. B. Cui, H. Kobayashi, Y. Einaga, and O. Sato The Light-induced Exited Spin State Trapping Effect on Ni(dmit)2 Salt with an Fe(III) Spin-crossover Cation: [Fe(qsal)2][Ni(dmit)2]2CH3CN Chem. Lett. 34(9), 1240-1241 (2005). S. S. Staniland, W. Fujita, Y. Umezono, K. Awaga, S. J. Clark, H. B. Cui, H. Kobayashi, and N. Robertson A Unique New Multiband Molecular Conductor: [BDTA][Ni(dmit)2]2 Chem. Commun., 25, 3204-3206 (2005).　　 H. B. Cui, S. Otsubo, Y. Okano, and H. Kobayashi Structural and Physical Properties of λ-(BEST)2MCl4 (BEST = bis(ethylenediseleno)tetrathiafulvalene; M = Fe, Ga) and Analogous Magnetic Organic Conductor Chem. Lett. 34(2), 254-255 (2005). H. Kobayashi, H. B. Cui, and A. Kobayashi Organic Metals and Superconductors Based on BETS (BETS = bis(ethylenedithio)tetraselenafulvalene) Chem. Rev. 104(11), 5265-5288 (2004). T. Otsuka, H. B. Cui, H. Fujiwara, H. Kobayashi, E. Fujiwara, and A. Kobayashi The Pressure Effect on the Antiferromagnetic and Superconducting Transitions of κ-(BETS)2FeBr4"BR> J. Mater. Chem., 14(11), 1682-1685 (2004). H.-J. Lee, H. B.. Cui, H. Fujiwara, H. Kobayashi, E. Fujiwara, and A. Kobayashi Development of New Magnetic Organic Conductors Based on Donor Molecules with Stable Organic Radical Part J. Phys. IV, 114, 533-535 (2004). H. Fujiwara, H-J. Lee, H. B. Cui, H. Kobayashi, E. Fujiwara, and A. Kobayashi Synthesis, Structure, and Physical Properties of a New Organic Conductor Based on a Π-Extended Donor Containing a Stable 2,2,5,5-Tetramethyl-1-pyrrolidinyloxy Radical Adv. Mater., 16(19), 1765-1769 (2004). H. B. Cui, T. Otsuka, A. Kobayashi, N. Takeda, M. Ishikawa, Y. Misaki, and H. Kobayashi Structural, Electrical and Magnetic Properties of a Series of Molecular Conductors Based on BDT-TTP and Lanthanoid Nitrate Complex Anions, [BDT-TTP = 2,5 - bis (1,3 - dithiol - 2 - ylidene) - 1,3,4, 6- tetrathiapentalene] Inorg. Chem., 42, 6114-6122, 2003. H. B. Cui, T. Otsuka, A. Kobayashi, Y. Misaki, and H. Kobayashi Synthesis and Physical Properties of New Molecular Conductors Based on Lanthanoid Chlorid Complex Anions Synth. Met., 135(1-3), 641-642 (2003). H. B. Cui, T. Otsuka, A. Kobayashi, Y. Misaki, and H. Kobayashi Structural and Electrical Properties of Novel Molecular Conductors Based on Extended-TTF Donors BDT-TTP and I-Anions Bull. Chem. Soc. Jpn., 76(1), 97-102 (2003). T. Otsuka, H.B. Cui, A. Kobayashi, Y. Misaki, and H. Kobayashi Magnetism of Metallic Molecular Crystals with Rare-earth Complex Anions J. Solid State Chem., 168(2), 444-449 (2002). ⇒　研究室メンバー　に戻る